 |
 |
 |
 |
 |
 |
 |
 |
 |
 |
Improved Reaction Data Heat Up The Biofuels Harvest
Wahsington DC (SPX) Aug 08, 2008 High food prices, concern over dwindling supplies of fossil fuels and the desire for clean, renewable energy have led many to seek ways to make ethanol out of cellulosic sources such as wood, hay and switchgrass. But today's processes are notoriously inefficient. In a new paper, researchers at the National Institute of Standards and Technology (NIST) have detailed some of the most fundamental processes involved in extracting sugars from biomass, the first step in producing ethanol by fermentation. Their findings should help engineers to improve their process designs in order to extract the maximum amount of fuel from a given measure of biomass. Most of the ethanol produced in the United States is created by fermenting the sugars and starch found in corn. The capability to convert inedible plants and agricultural waste into usable sources for ethanol production will help to supplement alternatives to fossil fuels while reducing the diversion of food crops to energy uses. Glucose can be extracted from two substances found in most plants: cellulose, the long molecule chains that comprise the cell walls of green plants, and its flimsier cell-wall counterpart, hemicellulose. The extracted glucose is then easily converted by fermentation to ethanol. NIST researchers, in collaboration with the National Renewable Energy Laboratory in Golden, Colo., have defined the theoretical limits of reactions important to cleaving, or breaking apart, cellulose and hemicellulose to produce glucose. They also determined that the energy needed to rupture these key bonds is a constant value for each molecular bond that is broken during the cleavage reactions. According to Yadu Tewari, Brian Lang and Robert Goldberg, chemists at NIST and co-authors of the paper, cellulose and hemicellulose both present problems to would-be ethanol producers. "Cellulose and hemicellulose are recalcitrant," Goldberg says. "They don't want to break down. It takes a long time for wood to rot. It even takes termites a long time to break wood down, and they're pretty good at it. Ethanol producers face the same problem. Because of the way these molecules are arranged, it's difficult to get access to the reactive centers in wood and other biomass. What we have done is to study some of the most basic reactions associated with the breakdown of these materials." With enzymes to speed the reactions, the team used calorimetry and chromatography to measure the thermodynamic property values of several reactions associated with the breakdown of cellulosic and hemicellulosic substances. Because process design and bioengineering benefit from the availability of these values, the data obtained in this investigation represent a "small but significant step toward maximizing the efficiency of biomass utilization," Tewari says. Community Email This Article Comment On This Article Share This Article With Planet Earth
Related Links National Institute of Standards and Technology (NIST) Powering The World in the 21st Century at Energy-Daily.com
Miscanthus Can Meet US Biofuels Goal
Champaign IL (SPX) Aug 08, 2008In the largest field trial of its kind in the United States, researchers have determined that the giant perennial grass Miscanthus x giganteus outperforms current biofuels sources - by a lot. |
|
|
| The content herein, unless otherwise known to be public domain, are Copyright 1995-2007 - SpaceDaily.AFP and UPI Wire Stories are copyright Agence France-Presse and United Press International. ESA Portal Reports are copyright European Space Agency. All NASA sourced material is public domain. Additional copyrights may apply in whole or part to other bona fide parties. Advertising does not imply endorsement,agreement or approval of any opinions, statements or information provided by SpaceDaily on any Web page published or hosted by SpaceDaily. Privacy Statement |
del.icio.us
Digg
Reddit
YahooMyWeb
Google
Facebook